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Nitrenes are the ghosts of synthetic chemistry, formed in an instant and gone just as quickly, rearranging into something entirely different. These highly reactive intermediates are widely used in synthesis, yet remain notoriously difficult to study because they rapidly transform

Brown University chemists have provided direct evidence that upends the textbook explanation of how triple chemical bonds work in heavy elements. In a study published in Science, the researchers show evidence that when atomic nuclei are sufficiently heavy, the principles describe

Progress in chemistry is often gradual, with some of its most important advances taking years—sometimes decades—to unfold. A case in point is the discovery of a novel "ferrocenophane" from the class of compounds known as "sandwich molecules"—so named because of their particular s